SCIENCE FILE
So elemental: Periodic table turns 150
One of history’s greatest scientific achievements has a fascinating backstory.

The periodic table has become an icon of science. Its rows and columns provide a tidy way of showcasing the elements — the ingredients that make up the universe.
It seems obvious today, but it wasn’t to generations of early chemists. That changed when Dmitri Mendeleev started writing a textbook and pondered ways to group the elements together in order to lighten his load.
The Russian chemist spotted an elegant and powerful pattern: He recognized that certain elements exhibited similar traits, and that these traits varied regularly — or periodically — with increasing atomic weight.
So on Feb. 17, 1869 (according to the Julian calendar used in Russia at that time), Mendeleev published a chart of the 60-odd elements known at the time, sorted by their weights and properties. He called it “An Attempt at a System of Elements, Based on Their Atomic Weight and Chemical Affinity.”
It has come to be regarded as one of the greatest scientific contributions of all time.
That’s why the United Nations and the International Union of Pure and Applied Chemistry are celebrating the 150th anniversary of Mendeleev’s periodic table. The festivities kicked off in Paris on Tuesday.
The journal Science is marking the occasion with a special issue about the table, which includes an essay on its origins by Michael Gordin, a science historian at Princeton University.
Gordin spoke with The Times about Mendeleev’s invention and its scientific legacy. This interview was edited for length and clarity.
So, in addition to increasing atomic weight, he saw that there is some other pattern that repeats. He’s the one who invented the term “periodic.”
Over time, he became more convinced that he had discovered a law of nature. That’s normal for scientific findings — when you first propose something, you don’t know it’s true yet.
The second thing is that he predicted the existence of new elements. When those elements are discovered, his table stands out.
The third reason is that he was very insistent during his lifetime that he deserved credit for the periodic table.
When Mendeleev started lining up elements with similar properties into columns, he noticed that, in some places, an element seemed to be in the wrong place and should be one column over. When he moved it over, everything worked out. But then there’s an empty gap. And he’s like, “OK, how do I explain what’s in the gap?”
He said, “Well, its atomic weight should be about this, because I can average from the elements around it and guess it.” And he’s like, “I know what its crystal structure should be. And I know something about what kinds of acids it would form, because it has those properties of the elements above and below it.”
Within 15 years, three of the elements he predicted in detail were discovered. And they had exactly the properties he said they would.
Then, in 1860, there was an international meeting of chemists in Germany. Mendeleev happened to be there because he was studying nearby. They propose a unified way of organizing the atomic weights, and when they do that, they correct a whole bunch of atomic weights.
Within a year or two, people started seeing these patterns.
The other organized elements by their ability to bond together. So you would create a table and say, sulfur bonds really well with this and this and this, in this order. They look like periodic tables, but they are totally different. They don’t list all of the elements, and things appear several times.
He was very boisterous, kind of funny, quick to lose his temper, but also clearly very charismatic and engaging. He was also very politically active. He was in the papers a lot.
After he finished the table, he decided he would start keeping all of his mail and all of his letters because he knew he would be famous. He’s the kind of person who cared about his legacy and thought of himself quite well.
Mendeleev didn’t know any of that. The electron was discovered in 1897, and he didn’t like that idea. He didn’t like many of these new ideas. When people discovered new things he couldn’t put in the table, he got very frustrated. It bothered him.
But later, Niels Bohr, the Danish physicist who’s one of the architects of quantum theory, published a very interesting version of the periodic table that incorporates the insights of the quantum vision of the atom to help explain how the system works.
It silenced those who thought the table was just a lucky guess.
We now understand why there are as many columns in the table as there are, and how many rows down we can go before the atom becomes too unstable. We now have a table with no gaps, and that gives us a real feeling of understanding nature.
But I think he would have been very gratified that the table is still omnipresent — that this thing he did is still around.

